Chemically expanded graphite-based ultra-high molecular weight polyethylene nanocomposites with enhanced mechanical properties

نویسندگان

چکیده

Chemically expanded graphite (CEG) has recently been identified as promising reinforcement for polymer composites with the ability commercial up-scaling. In this work, silane and polydopamine functionalized CEG were successfully synthesized employed to prepare ultra-high molecular weight polyethylene (UHMWPE) nanocomposites an enhanced interfacial compatibility. Characterisation of indicated a significant oxygen reduction, which gave rise restoration graphitic structure. The showed exfoliation dispersion in organic solvents matrix respect non-modified CEG. provided higher affinity towards chains covering sheets on fracture surfaces. addition mechanical properties UHMWPE increase micro-hardness up 25% storage modulus 58%. Furthermore, hydrophobicity was significantly water contact angle from 98.6° pure 119° 5 wt% Preliminary wear experiments potential tribological applications decrease rate 99% under lubricated conditions.

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ژورنال

عنوان ژورنال: Materials & Design

سال: 2022

ISSN: ['1873-4197', '0264-1275']

DOI: https://doi.org/10.1016/j.matdes.2022.111304